Journal
ORGANIC LETTERS
Volume 3, Issue 8, Pages 1221-1224Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0157104
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The alpha -deprotonation of alkynyl carbamates 3 with the chiral base (-)-sparteine (4)/n-butyllithium, transmetalation with CITi((OPr)-Pr-/)B-3 and subsequent substitution with an aldehyde results in the formation of enantioenriched 4-hydroxyallenyl carbamates 11. Stereoselection is determined by dynamic resolution of the lithium/(-)-sparteine complexes by selective crystallization.
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