Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 34, Issue 5, Pages 359-369Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar990114j
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An essential aspect of the development of organic based electronics is the synthetic chemistry devised for the preparation of the semiconductor materials responsible for the activity of organic field-effect transistors. Access to organic semiconductors in sufficient purity and variety has led to breakthroughs in solid-state physics and circuit realization. In this Account, we review the synthetic methods that have been most useful for preparing a range of semiconductors, including thiophene-based oligomers, several kinds of fused rings, and polymers. The tradeoff between process efficiency and target purity is emphasized.
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