Journal
CHEMOSPHERE
Volume 43, Issue 4-7, Pages 783-785Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0045-6535(00)00434-3
Keywords
polychlorinated biphenyls; chlorobenzenes; formation; condensation; mechanism
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Polychlorinated biphenyls (PCBs) were formed by pyrolysis of chlorobenzenes in a HCl atmosphere. Varieties of substituted chlorobenzenes were used as model compounds to optimize the condensation reaction. Lower chlorinated benzenes produce more PCBs than that of higher ones. Up to 0.7 mug PCBs/mg 1,2,3-trichlorobenzene was produced through the condensation reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.
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