Journal
EUROPEAN POLYMER JOURNAL
Volume 37, Issue 5, Pages 1071-1074Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0014-3057(00)00208-1
Keywords
benzyl methacrylate; neopentyl glycol dimethacrylate; Lauryl mercaptan; proliferous polymerization; popcorn formation; crosslinking
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The anomalous popcorn formation in the presence of a large amount of lauryl mercaptan as a chain transfer agent was explored in the free-radical crosslinking copolymerization of benzyl methacrylate with neopentyl glycol dimethacrylate, Thus, the radical accumulation during proliferous polymerization was pursued ESR-spectroscopically and a brief mechanistic discussion is described. (C) 2001 Elsevier Science Ltd. All rights reserved.
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