Journal
RUSSIAN CHEMICAL BULLETIN
Volume 50, Issue 5, Pages 828-832Publisher
CONSULTANTS BUREAU
DOI: 10.1023/A:1011350908009
Keywords
haloadamantanes; gas chromatography; adsorption; thermodynamic characteristics of adsorption; molecular statistic theory; cage effect; stationary phases; retention indices
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The main thermodynamic characteristics of the adsorption of haloadamantanes on graphitized thermal carbon black were determined by experimental measurements and by calculations in terms of molecular-statistic theory of adsorption. Using experimental data, the Kovac retention indices were calculated and the optimum conditions for gas-chromatographic separation of haloadamantanes on stationary phases with different polarity were elucidated. The influence of the cage effect in the adamantane unit on the chromatographic properties of haloadamantanes was established.
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