Journal
TETRAHEDRON LETTERS
Volume 42, Issue 19, Pages 3339-3342Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00427-0
Keywords
(salen)manganese(III) complex; asymmetric C-H amination; benzylic amination; allylic amination
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A chiral 3.3',5,5'-tetrabromosubstituted (salen)manganese(III) complex was found to be an efficient catalyst for asymmetric Cn amination (up to 89% ee). In the reaction of cycloalkenes, allylic amination occurred in preference to aziridination, (C) 2001 Elsevier Science Ltd. All rights reserved.
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