Journal
MACROMOLECULES
Volume 34, Issue 10, Pages 3155-3158Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma0019611
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The efficient, controlled polymerization of 2-hydroxyethyl methacrylate (HEMA) is achieved using atom transfer radical polymerization in methanol/water mixtures or pure methanol at 20 degreesC. The evolution of molecular weight with conversion is linear; polydispersities are around 1.1 for polymerization in methanol and around 1.2-1.3 for syntheses in 50:50 methanol/water mixtures, indicating good living character.
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