☆ 4.4 Article

Tetrakis(dimethylamino)ethylene (TDAE) mediated addition of difluoromethyl anions to heteroaryl thiocyanates.: A new simple access to heteroaryl-SCF2R derivatives

TETRAHEDRON LETTERS (2001)

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Journal

TETRAHEDRON LETTERS
Volume 42, Issue 20, Pages 3463-3465

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00514-7

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Categories

Chemistry, Organic

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New heteroaryl-SCF2R derivatives 8-13 are easily obtained in one-pot from the tetrakis(dimethylamino)ethylene (TDAE) mediated reduction of halogenodifluoromethyl substrates RCF2X 1-4 in the presence of heteroaryl-thiocyanates 5-7. (C) 2001 Elsevier Science Ltd. All rights reserved.

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