Journal
ORGANIC LETTERS
Volume 3, Issue 10, Pages 1503-1505Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol015816z
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The addition of stoichiometric quantities of water accelerates both the trimethylaluminum mediated aromatic Claisen reaction and the chiral zirconocene-catalyzed asymmetric carboalumination of terminal alkenes, The two reactions occur in a tandem sequence resulting in the selective formation of two new C-C and one C-O bond after oxidative quench of the intermediate trialkylalane.
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