4.8 Article

Asymmetric intramolecular C-H insertions of aryldiazoacetates

Journal

ORGANIC LETTERS
Volume 3, Issue 10, Pages 1475-1477

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol0157858

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[GRAPHICS] The enantioselectivity of Rh-2(SDOSP)(4) catalyzed C-H insertion of aryldiazoacetates is very dependent on the site of the C-H insertion. The highest enantioselectivity is obtained for insertion into methine C-H bonds.

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