Journal
TETRAHEDRON-ASYMMETRY
Volume 12, Issue 8, Pages 1147-1150Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0957-4166(01)00144-6
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The new chiral heterobimetallic complex Sc(BINOL)(2)Li 1 was prepared and used as a catalyst in the enantioselective addition of a cyanide source (HCN or TMSCN) to several imines. High conversion rates and enantiomeric e excesses (e.e.s) as high as 95% were obtained. (C) 2001 Elsevier Science Ltd. All rights reserved.
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