Synthesis and characterisation of silver, zinc and cadmium compounds with an N3O2 Schiff base macrocycle:: the crystal and molecular structures of the silver(I) and cadmium(II) complexes

The metal-templated cyclocondensation of 2,6-diformylpyridine and 1,4-bis(2-aminophenoxy)butane in the presence of silver(I), zinc(II) and cadmium(II) salts gave the following di-imine macrocyclic complexes: [AgL](ClO4) (1), [ZnL](ClO4)(2). 2H(2)O (2), [ZnL](NO3)(2) (3), [CdL(H2O)(2)](ClO4)(2) (4) and [CdL(NO3)(CH3OH)](NO3) (5) (L = macrocyclic ligand). All compounds have been characterised by microanalysis, IR, conductivity measurements, MS-FAB and H-1 NMR spectroscopic studies. Compounds 1, 4 and 5 were also studied by single-crystal X-ray diffraction. (C) 2001 Elsevier Science B.V. All rights reserved.