4.4 Article

Palladium-catalyzed carbonylative cross-coupling reactions of pyridine halides and aryl boronic acids:: a convenient access to α-pyridyl ketones

Journal

TETRAHEDRON LETTERS
Volume 42, Issue 22, Pages 3689-3691

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00544-5

Keywords

carbonylation; cross-coupling; ketones; palladium; pyridines

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The proper choice of solvent, catalyst precursor and CO pressure enables the easy and selective transformation of mono- and dihalopyridines into phenyl pyridyl ketones in 81-95%, yields. (C) 2001 Elsevier Science Ltd. All rights reserved.

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