4.2 Article

Reaction of 2-chloro-1-azaazulene with diphenylcyclopropenone;: Dimerization of the cycloadduct attended by cine-substitution and rearrangement

Journal

HETEROCYCLES
Volume 55, Issue 6, Pages 1189-1194

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-01-9224

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2-Chloro-1-azaazulene reacted with diphenylcyclopropenone to give 3,4-diphenyl-2a,5-dihydro-2H-2a-azabenz[cd]azulene-2,5-dione and 6-[(3,4-diphenyl-5-oxo-2a,5-dihydro-2H-2a-azabenz[cd]azulen-2-ylidene)-methyl]-3,4-diphenyl-2a,5-dihydro-2a-azaacenaphtylen-5-one; the latter would be produced via cycloaddition and at successive cine-substitution followed by rearrangement.

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