Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 505, Issue 1-2, Pages 170-172Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-0728(01)00477-6
Keywords
corrole; oxidation; protonation; spectro-electrochemistry
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Octaethylcorrole (H3OEC) has been studied electrochemically in methylene chloride. In contrast with what is commonly observed in tetrapyrrolic macrocycles, no radical cation was detected after a one-electron oxidation. Instead, the protonated species [H4OEC](+) was obtained. [H4OEC](+) was easily converted back to the initial corrole by electrochemical reduction. (C) 2001 Elsevier Science B.V. All rights reserved.
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