4.6 Article

Adsorption equilibria of bio-based butanol solutions using zeolite

Journal

BIOCHEMICAL ENGINEERING JOURNAL
Volume 48, Issue 1, Pages 99-103

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.bej.2009.08.014

Keywords

Bioseparations; Adsorption; Bioresources; Biofuels; Butanol; Zeolite

Funding

  1. Netherlands Ministry of Economic Affairs
  2. B-Basic partner organizations

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1-Butanol can be produced by clostridial fermentations with acetone and ethanol as by-products The butanol can be present up to similar to 20 g L-1 depending on process conditions and microbial strain The high-silica zeolite CBV28014 has been proven to adsorb butanol selective over water, while showing higher affinity for butanol than for acetone and ethanol Multi-component acetone-butanol-ethanol (ABE) adsorption on CBV28014 has been modeled using a single site extended Langmuir adsorption model and the ideal adsorbed Solution (IAS) theory model The IAS model describes multi-component adsorption of ABE in synthetic mixtures and ABE in filtered fermentation broth by CBV28014 more accurately than the single site extended Langmuir model (C) 2009 Elsevier B V All rights reserved

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