Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 114, Issue 21, Pages 9402-9407Publisher
AMER INST PHYSICS
DOI: 10.1063/1.1370081
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Multichannel quantum defect theory (MQDT) is applied within a unified framework to compute the ionization and dissociation channel phases of HI. Our numerical results illustrate the mathematical origin of a channel phase within the MQDT formalism, and are consistent with the existing theory of this phenomenon, based on the collision formalism and with experimental measurements. The present study explains why previous MQDT calculations predicted that the channel phase vanishes identically. (C) 2001 American Institute of Physics.
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