Journal
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS
Volume 40, Issue 6A, Pages L561-L563Publisher
INST PURE APPLIED PHYSICS
DOI: 10.1143/JJAP.40.L561
Keywords
titanium dioxide; doping; nitrogen; substitutional; band gap
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TiO2-based powder, including 0.1 at% of N doped in the rutile lattice. has been synthesized by oxidation of TiN. As a result, a significant shift of the absorption edge to a lower energy in the visible-light region has been observed. The substitutional doping of N into the TiO2 lattice is found to be effective; its 2p states contribute to the band-gap narrowing by mixing with O 2p as shown in ab initio electronic structure calculations.
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