Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 66, Issue 11, Pages 3820-3827Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo010025w
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Funding
- NCI NIH HHS [CA 09112] Funding Source: Medline
- NIGMS NIH HHS [GM 46059, GM 58160] Funding Source: Medline
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The preparations of polymer-supported dialkylphosphinobiphenyl ligands (3) are reported. A palladium catalyst based on ligand 3a is active for amination and Suzuki reactions using unactivated aryl iodides, bromides, or chlorides. Filtration of the catalyst from the reaction mixture allows for simplified product isolation via an aqueous workup. The resin-bound catalyst can be recycled without additional palladium in both the amination and Suzuki reactions.
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