Journal
TETRAHEDRON LETTERS
Volume 42, Issue 24, Pages 4049-4052Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00626-8
Keywords
hydrogen peroxide; sulfoxides; manganese; oxidation
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In situ prepared manganese complexes with ligands 1-5 have been used in the catalytic oxidation of sulfides to sulfoxides using hydrogen peroxide at 0 degreesC in acetone. Using ligand 4, methyl phenyl sulfoxide is obtained in 55% yield and turnover numbers up to 250, while the formation of sulfone is almost suppressed. (C) 2001 Elsevier Science Ltd. All rights reserved.
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