Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 171, Issue 1-2, Pages 37-42Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1381-1169(01)00098-X
Keywords
oxidation; porphyrin; hydrogen peroxide; hexafluoroacetone
Categories
Ask authors/readers for more resources
The catalytic oxidation of cyclohexene with hydrogen peroxide promoted by manganese and iron porphyrins has been studied in the presence of halogenated carbonyl compounds as co-catalysts in a dichloromethane/water biphasic medium. The efficiency of the overall catalytic process is strictly related to the nature of the co-catalyst and to the high reactivity of its perhydrate form toward metalloporphyrins in forming an high valent oxo-pororphyrin derivative. Hydrogen peroxide fixation by hexafluoroacetone hydrate provides an useful system to hamper catalyst bleaching and/or oxidant decomposition. Thus, a complete olefin conversion into oxygenated products is accomplished with a very limited excess of oxidant respect to the organic substrate. (C) 2001 Elsevier Science B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available