Journal
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
Volume 39, Issue 13, Pages 1529-1547Publisher
JOHN WILEY & SONS INC
DOI: 10.1002/polb.1126
Keywords
viscoelastic diffusion; differential sorption experiments
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A constitutive equation is proposed for the viscoelastic diffusion flux, and this equation is used to calculate sorption curves for differential step-change sorption experiments. The predictions of the theory are shown to be consistent with eight experimental observations that report a wide range of diffusional behaviors for polymer-solvent systems. (C) 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 1529-1547, 2001.
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