Journal
TETRAHEDRON LETTERS
Volume 42, Issue 27, Pages 4441-4444Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00793-6
Keywords
asymmetric catalyst; asymmetric synthesis; Michael reaction
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Enantioselective direct Michael additions of ketones using (S)-1-(2-pyrroldinylmethyl)-pyrrolidine as a catalyst are described. Michael adducts with up to 91% e.e. were obtained by the reaction of alkylidene malonates with simple unactivated ketones under mild reaction conditions. (C) 2001 Elsevier Science Ltd. All rights reserved.
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