Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 105, Issue 26, Pages 6061-6063Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp010794j
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For the decomposition of pure water to hydrogen and oxygen, MIn2O4 (M = Ca, Sr), Sr2SnO4, and NaSbO3 were found to make stable photocatalysts when combined with RuO2. The metal oxides are composed of the d(10) p-block metal ions (In3+, Sn4+, and Sb5+), and it is demonstrated that the p-block metal oxides with d(10) configuration form a new photocatalyst group different from the conventional metal oxide photocatalyst group consisting of the octahedrally coordinated d(0) transition-metal ions such as Ti4+, Zr4+, Nb5+, and Ta5+.
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