4.4 Article

Arylation of α-substituted acrylates in ionic liquids catalyzed by a Pd-benzothiazole carbene complex

Journal

TETRAHEDRON LETTERS
Volume 42, Issue 28, Pages 4701-4703

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00795-X

Keywords

beta-aryl ketones; ionic liquids; carbenes; Heck reaction

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A Pd-catalyst with benzothiazole carbene as ligands allows, in tetrabutylammonium bromide melt as solvent, very fast and efficient reactions of bromoaromatics with 3-hydroxy-2-methylenealkanoates to give beta -arylketones. (C) 2001 Published by Elsevier Science Ltd.

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