Journal
ORGANIC LETTERS
Volume 3, Issue 14, Pages 2225-2228Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol016103j
Keywords
-
Categories
Funding
- NIGMS NIH HHS [R01 GM039754, GM 39754] Funding Source: Medline
Ask authors/readers for more resources
[GRAPHICS] We propose that controversy concerning the mechanism for solvolysis at tertiary carbon is semantic and can be avoided by making a clear distinction between (1) nucleophilic solvent participation, which is stabilization of the transition state for concerted solvolysis by formation of a partial covalent bond to the solvent nucleophile, and (2) nucleophilic solvation, which is stabilization of the transition state for stepwise solvolysis through carbocation or ion pair intermediates by charge-dipole interactions with nucleophilic solvents,
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available