4.6 Article

Memory of chirality in the non-Kolbe reaction of N-arylcarbonylated L-prolines

Journal

JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 507, Issue 1-2, Pages 71-74

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-0728(01)00404-1

Keywords

amino acids and derivatives; electrochemistry; oxidation; asymmetric reactions

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The non-Kolbe reaction of N-arylcarbonylated L-prolines in methanol gave the decarboxylated alpha -methoxyamine derivatives, which retained the original chirality to some extent, presenting a new memory of chirality in carbenium ion chemistry. (C) 2001 Elsevier Science B.V. All rights reserved.

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