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Chromotropism of coordination compounds and its applications in solution

Journal

COORDINATION CHEMISTRY REVIEWS
Volume 218, Issue -, Pages 113-152

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/S0010-8545(01)80005-9

Keywords

solvatochromism; donor number; acceptor number; thermochromism; piezochromism; photochromism; magnetochromism; valence tautomerism

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Chromotropic properties of coordination varying solvent, ionic species in solution, temperature, pressure, magnetic field or light irradiation are reviewed. Structural varieties and changeabilities of coordination compounds connected with these effects are discussed. Applications of solvatochromic Lewis-acid and Lewis-base indicators are presented in some detail. (C) 2001 Elsevier Science B.V. All rights reserved.

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