4.6 Article

Ostwald ripening: The screening length revisited

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SPRINGER-VERLAG
DOI: 10.1007/PL00009923

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We are interested in the coarsening of a spatial distribution of two phases, driven by the reduction of interfacial energy and limited by diffusion, as described by the Mullins-Sekerka model. We address the regime where one phase covers only a small fraction of the total volume and consists of many disconnected components (particles). In this situation, the energetically more advantageous large particles grow at the expense of the small ones, a phenomenon called Ostwald ripening. Lifshitz, Slyozov and Wagner formally derived an evolution for the distribution of particle radii. We extend their derivation by taking into account that only particles within a certain distance, the screening length, communicate. Our arguments are rigorous and are based on a homogenization within a gradient flow structure.

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