Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 570, Issue 1-3, Pages 25-35Publisher
ELSEVIER
DOI: 10.1016/S0022-2860(00)00868-1
Keywords
hydrogen bonding; phenolic resins; p-cresol/formaldehyde; calixarene
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The nature of the strong hydrogen bonds found in p-cresol/formaldehyde (PCF) resins, compared to ordinary phenolic compounds, is studied. The evidence from FTIR spectroscopy indicates that this strong interaction is due to intramolecular hydrogen bonding from calixarene-like structures. The formation of this structure in PCF is enabled by its linear (all-ortho-linkage) structure, which is not present in branched resins. Additionally, a transition is observed at around 175 to 200 degreesC where the intramolecular hydrogen bonded structure is lost. This structure cannot be recovered upon cooling or annealing due to restrictions on conformational rotations that are coupled to a new pattern of intermolecular hydrogen bonding. However, the structure is reformed by dissolving the resin in solution and casting new films. (C) 2001 Elsevier Science BN. All rights reserved.
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