Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 10, Issue -, Pages 2089-2121Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.10.218
Keywords
asymmetric catalysis; chiral phosphine; nucleophilic; organocatalysis; organophosphorus; synthesis
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Funding
- NIH [GM071779]
- National Natural Science Foundation of China [21172253, 21372256]
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This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita-Baylis-Hillman (MBH) acetates, carbonates, and ketenes with activated alkenes and imines, allylic substitutions of MBH acetates and carbonates, Michael additions, gamma-umpolung additions, and acylations of alcohols.
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