Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 10, Issue -, Pages 2421-2427Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.10.252
Keywords
aldol reaction; astakolactin; lactonization; MNBA; terpenoids
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Funding
- Center for Chirality
- Ministry of Education, Science, Sports and Culture, Japan
- Grants-in-Aid for Scientific Research [22350044] Funding Source: KAKEN
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The first total synthesis of the proposed structure of astakolactin, a sesterterpene metabolite isolated from the marine sponge Cacospongia scalaris, has been achieved, mainly featuring Johnson-Claisen rearrangement, asymmetric Mukaiyama aldol reaction and MNBA-mediated lactonization.
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