Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 10, Issue -, Pages 1272-1281Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.10.128
Keywords
alkene; cascade; endoperoxide; oxidation; photoredox catalysis
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Funding
- David and Lucile Packard Foundation
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Triarylpyrylium salts were employed as single electron photooxidants to catalyze a cyclization-endoperoxidation cascade of dienes. The transformation is presumed to proceed via the intermediacy of diene cation radicals. The nature of the diene component was investigated in this context to determine the structural requirements necessary for successful reactivity. Several unique endoperoxide structures were synthesized in yields up to 79%.
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