Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 9, Issue -, Pages 557-576Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.9.61
Keywords
amidyls; iminyls; radical allylation; radical vinylation; xanthate transfer
Categories
Funding
- Ecole Polytechnique
- CNRS
- MNRT
- DGA
- ANR
- Alfred Kastler Foundation
- CONACyT (Mexico)
- MECyD (Spain)
- Royal Commission for the Exhibition of 1851
- Rhodia
- Scynexis
- Sanofi-Aventis
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This review article describes briefly some of the radical processes developed in the authors' laboratory as they pertain to the concise assembly of complex molecular scaffolds. The emphasis is placed on the use of nitrogen-centred radicals, on the degenerate addition-transfer of xanthates, especially on its potential for intermolecular carbon-carbon bond formation, and on the generation and capture of radicals through electron transfer processes.
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