Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 9, Issue -, Pages 2635-2640Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.9.299
Keywords
alkenes; catalysis; copper; electrophilic trifluoromethylating reagent; trifluoromethylation
Categories
Funding
- National Natural Science Foundation of China [21032006, 21172240]
- 973 Program of China [2012CBA01200]
- Chinese Academy of Sciences
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An efficient method for the copper-catalyzed trifluoromethylation of terminal alkenes with an electrophilic trifluoromethylating reagent has been developed. The reactions proceeded smoothly to give trifluoromethylated alkenes in good to excellent yields. The results provided a versatile approach for the construction of C-vinyl-CF3 bonds without using prefunctionalized substrates.
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