Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 8, Issue -, Pages 1594-1600Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.8.182
Keywords
cyclodextrins; poly(viologen); supramolecular hydrogel
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Funding
- Japan Science and Technology Agency
- Grants-in-Aid for Scientific Research [23685026, 23655104] Funding Source: KAKEN
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Supramolecular materials with noncovalent bonds have attracted much attention due to their exclusive properties differentiating them from materials formed solely by covalent bonds. Especially interesting are rotor molecules of topological complexes that shuttle along a polymer chain. The shuttling of these molecules should greatly improve the tension strength. Our research employs cyclodextrin (CD) as a host molecule, because CD effectively forms polyrotaxanes with polymers. Herein we report the formation of supramolecular hydrogels with an alpha-CD dimer (alpha,alpha-CD dimer) as a topological linker molecule, and a viologen polymer (VP) as the polymer chain. The supramolecular hydrogel of alpha,alpha-CD dimer/VP forms a self-standing gel, which does not relax (G' > G '') in the frequency range 0.01-10 rad.s(-1). On the other hand, the supramolecular hydrogel decomposes upon addition of bispyridyl decamethylene (PyC10Py) as a competitive guest. Moreover, the beta-CD dimer (beta,beta-CD dimer) with VP does not form a supramolecular hydrogel, indicating that complexation between the C-10 unit of VP and the alpha-CD unit of the alpha,alpha-CD dimer plays an important role in the formation of supramolecular hydrogels.
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