Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 8, Issue -, Pages 1844-1848Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.8.212
Keywords
amidation; C-H activation; C-H functionalization; ferrocene; rhodium
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Funding
- Japan Society for the Promotion of Science (JSPS)
- Waseda University [2011A-896]
- Grants-in-Aid for Scientific Research [23850015] Funding Source: KAKEN
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[RhCp*(OAc)(2)(H2O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C-H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF4 center dot OEt2. A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectivities.
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