Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 7, Issue -, Pages 75-81Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.7.11
Keywords
amino acids; dicarboxylate ion recognition; enantioselectivity; mesitylene scaffold
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Funding
- University Grants Committee of the Hong Kong SAR, China [HKBU 200208]
- Direct For Mathematical & Physical Scien [0844602] Funding Source: National Science Foundation
- Division Of Chemistry [0844602] Funding Source: National Science Foundation
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Two mesitylene based neutral receptors 1 and 2 bearing two thiourea binding sites were constructed as fluorescent probes for sensing dicarboxylates. Their binding affinities toward dicarboxylates, aspartate and glutamate have been investigated in acetonitrile solution by fluorescence titration experiments. Both fluorescent sensors exhibited some ability to discriminate the antipodal forms of aspartate and glutamate.
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