Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 6, Issue -, Pages -Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.6.70
Keywords
1-aryltriazenes; N-heterocyclic carbene-palladium complex; polymer-supported catalyst; recyclable catalyst; Suzuki-Miyaura reaction
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Funding
- Natural Science Foundation of China [20962022]
- Chengdu Key Technologies R D Program
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The Suzuki-Miyaura cross-coupling reaction of 1-aryltriazenes with arylboronic acids catalyzed by a recyclable polymer-supported Pd-NHC complex catalyst has been realized for the first time. The polymer-supported catalyst can be re-used several times still retaining high activity for this transformation. Various aryltriazenes were investigated as electrophilic substrates at room temperature to give biaryls in good to excellent yields and showed good chemoselectivity over aryl halides in the reactions.
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