Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 5, Issue -, Pages -Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.5.77
Keywords
coordination polymers; crystal engineering; hydrogen-bonded networks; porphyrin assemblies; supramolecular chemistry
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Funding
- Israel Science Foundation [502/08]
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Crystal engineering studies confirm that the zinc-tetra(4-pyridyl)porphyrin building block reveals versatile supramolecular chemistry. In this work, it was found to be reactive in the assembly of both (a) a 2D polymeric array by a unique combination of self-coordination and coordination through external zinc dichloride linkers and (b) an extended heteromolecular hydrogen-bonded network with mellitic acid sustained by multiple connectivity between the component species.
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