Journal
TETRAHEDRON
Volume 57, Issue 32, Pages 7047-7051Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(01)00677-9
Keywords
KF-Al2O3 acetylation; chemoselectivity; solvent effect
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KF-Al2O3 brings about rapid acetylation of a range of amines, alcohols, and phenols with Ac2O/AcCl. Aliphatic alcohols are acetylated chemoselectively in the presence of phenols. 1 degrees alcohols react several times faster than 2 degrees alcohols. 3 degrees alcohols do not react. (C) 2001 Elsevier Science Ltd. All rights reserved.
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