Journal
ORGANOMETALLICS
Volume 20, Issue 16, Pages 3367-3369Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om010395a
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Stable group 13 metal chlorobenzene complexes of general type [(Pr-i(2)-ATI)MR][B(C6F5)(4)](ClPh) (M = Al, Ga, In; Pr-i(2)-ATI = N,N ' -diisopropylaminotroponiminate) have been isolated. X-ray crystallographic studies show that the PhCl ligands in these compounds are coordinated by dative M-ClPh bonding and suggest that pi -stacking interactions between the PhCl phenyl ring and the iPr2-ATI ligand may also contribute to the PhCl coordination.
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