4.5 Article

The first synthesis of ferrocenyl aminophosphonic esters

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 631, Issue 1-2, Pages 105-109

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(01)01011-7

Keywords

ferrocenecarboxaldehyde; Schiff bases; aminophosphonates; asymmetrical induction; ferrocene moiety

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The series of aminophosphonates bearing the ferrocenyl moiety was obtained by the addition of dialkyl phosphites to an azomethine bond of Schiff bases. Some successful attempts to perform the asymmetrical synthesis of aminophosphonates were made, but the isolation of diastereomers failed. (C) 2001 Elsevier Science B.V. All rights reserved.

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