Journal
ORGANOMETALLICS
Volume 20, Issue 17, Pages 3635-3637Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om010212k
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Reactions of hydrophilic unsymmetrical pyridine-imine chelating ligands with pt(eta (2)-norbornene)(3) in the presence of olefins that contain electron-withdrawing substituents afford water-soluble three-coordinate Pt-(0) complexes. The stability of these organometallic complexes in aqueous solution is dependent on the position of the hydrophilic charged substituents in the chelating ligand and the electronic nature of the coordinated olefin.
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