Catalytic asymmetric dihydroxylation using phenoxyethoxymethyl-polystyrene (PEM)-Based novel microencapsulated osmium tetroxide (PEM-MC OsO4)

[GRAPHICS] A phenoxyethoxymethyl-polystyrene (PEM)-based novel polymer-supported osmium catalyst has been developed. The catalyst was readily prepared from PEM polymer based on a microencapsulation technique, and asymmetric dihydroxylation of olefins has been successfully performed using (DHOD)(2)PHAL as a chiral ligand and K3Fe(CN)(6) as a cooxidant in H2O/acetone. The catalyst was recovered quantitativery by simple filtration and reused without loss of activity several times.