Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 66, Issue 17, Pages 5664-5670Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo015764r
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New dipolar and non-dipolar poly(phenylenevinylene) dendrimers bearing electron-donating and electron-withdrawing groups have been efficiently synthesized using Heck and Horner-Wadsworth-Emmons reactions. The photoluminescence of these systems may be tuned in the blue zone by choosing the appropriate peripheral groups. Despite the meta-substitution pattern, large Stokes shifts can be observed when pi -donor and pi -acceptor groups are connected by a m-phenylenevinylene system.
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