Journal
ELECTROCHIMICA ACTA
Volume 46, Issue 26-27, Pages 4205-4211Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0013-4686(01)00700-9
Keywords
electrosynthesis; polypyrrole; palladium nanoparticles; nanostructured composites; conducting polymers
Categories
Ask authors/readers for more resources
Palladium-polypyrrole nanostructured composite films can be easily synthesised using a two-step procedure comprising the electrochemical synthesis of palladium nanoparticles (Pd-NPs) that are subsequently po ten tio statically deposited onto a polypyrrole thin film electrosynthesised from an acetonitrile solution. The composite thin films have good conductivity and their transmission electron micrographs show that the metallic inclusions have a mean diameter of about 5 nm with a homogeneous size distribution. X-ray photoelectron spectroscopy (XPS) analysis reveals the presence of two surface oxidation states for the as-synthesised Pd-NPs as well as for those deposited on the films. On the basis of experimental findings, a structural model for the Pd-NPs is proposed. (C) 2001 Elsevier Science Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available