Journal
COORDINATION CHEMISTRY REVIEWS
Volume 219, Issue -, Pages 53-80Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0010-8545(01)00299-5
Keywords
molecular electrochemistry; redox processes; electron-transfer; isomerization; mechanisms; octahedral complexes
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Geometrical isomerization processes induced electrochemically are reviewed for octahedral-type complexes, in particular with pi -electron acceptor ligands, with focus on those whose mechanisms have been established in terms of square ECEC-type schemes and electron-transfer chain catalysis. Rationalizations based on the isomeric redox potential differentiation are also presented. (C) 2001 Elsevier Science B.V. All rights reserved.
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