Journal
ORGANOMETALLICS
Volume 20, Issue 18, Pages 3962-3965Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om010282r
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The title compound adds to alpha,beta- unsaturated carbonyls to give the products of 1,4-addition after hydrolysis of the intermediate boron enolates, in 68-86% isolated yield (four examples). In addition, we discovered that diazomethane reacts with bis(pinacolato)diborane to insert methylene to give (pinacolato)(2)BCH2B in 83% yield. An alternative synthesis involved coupling of (pinacolato)BCH2I with various metals.
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