Journal
ORGANIC LETTERS
Volume 3, Issue 18, Pages 2887-2890Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0163474
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[GRAPHICS] Macromolecules 1c and 2c, bearing multiple redox-active sites are synthesized by an efficient palladium-catalyzed coupling of 2,5-dimethoxytolylmagnesium bromide with readily available hexakis(4-bromophenyl)benzene and tetrakis(4-bromophenyl)methane. These macromolecular electron donors undergo reversible oxidation at a constant potential of 1.15 V vs SCE to yield robust, multiply charged cation radicals that are isolated in pure form using SbCl5 as an oxidant. These nanometer-size cation-radical salts are shown to act as efficient electron sponges toward a variety of electron donors.
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